气袋采样法对还原硫化物测定的影响因素分析及机理研究     

孟洁  翟增秀  刘英会  张君  韩萌 《岩矿测试》2019,38(2):179-185

还原硫化物是一Z类典型的恶臭物质,其特点是活性高、不易储存,因此适宜的储存条件对还原硫化物的准确测定具有重要意义。本文使用气相色谱-质谱联用技术,从气袋材质、还原硫化物初始浓度、还原硫化物性质和储存时间四个因素探究袋采样法储存还原硫化物过程的损失情况。以Tedlar~? PVF和Teflon~? FEP为目标采样袋,使用5个初始浓度(0. 001、0. 010、0. 100、1. 000和10. 000μg/m L)的混合还原硫化物,选择0、2、6、12、24、48以及72h的储存时间,以响应因子和相对回收率作为评价因子,并使用配对t检验法和吸附动力学,研究影响储存效果的主要因素、物质损失机理以及两种采样袋的储存能力。结果表明,储存时间越长、物质初始浓度越高,物质活性越强,损失情况越严重;在环境温度达到60℃时,Tedlar~? PVF的基质背景较Teflon~? FEP更复杂;相同条件下,还原硫化物在Teflon~? FEP储存过程中损失更严重。依据研究结果建议:(1)样品采集后避光保存;(2)低浓度含硫样品的测定在采样后8h内完成,高浓度含硫样品的测定在2h内完成;(3)若待测样品气体温度较高,优先选择Teflon~? FEP采样袋,气体温度较低条件下选择Tedlar~? PVF采样袋,可最大限度保持样品的原始状态。本研究成果有利于确保还原硫化物样品的储存稳定性,最大限度还原恶臭污染现场情况,为恶臭污染的分析测试以及后续的恶臭污染控制与治理提供技术支持。  相似文献   

原子荧光光谱测定土壤和水系沉积物中硒的干扰来源及消除方法     

赵宗生  赵小学  姜晓旭  赵林林  张霖琳 《岩矿测试》2019,38(3):333-340

原子荧光光谱法(AFS)具有灵敏度高、结构简单、容易操作等优点,但目前测定土壤和沉积物中的硒等元素的标准方法所采用的消解过程繁琐,易产生干扰。沸水浴可以把土壤和水系沉积物中硒提取完全,本文根据样品中元素丰度和仪器性能,将AFS测定Se的干扰分为Cu和Pb两大类,根据实验提出在水浴消解液加入浓盐酸(不宜加入硫脲-抗坏血酸),通过增加溶液酸度和Cl~-浓度,即保持样品中盐酸浓度高于23%,可抑制Cu~(2+)还原为Cu~0和Pb~(4+)生成PbH_4,有效降低了Cu的负干扰和Pb的正干扰,提高了AFS测定Se的精密度和准确度。本方法测定Se的检出限为0.008mg/kg,测试标准物质的相对标准偏差为0.5%～11%,相对误差为-16.3%～9.5%;比行业标准HJ 680—2013的检出限(0.01mg/kg)、精密度(0.79%～23.1%)和准确度等技术指标更佳。  相似文献   

GLDAS和CMIP5产品的中国土壤湿度-降水耦合分析及变化趋势   总被引：2，自引：0，他引：2  

张述文  刘源  曹帮军  李少英 《气候与环境研究》2016,21(2):188-196

利用GLDAS同化产品和12个CMIP5模式的输出结果,从土壤湿度对降水影响的两个中间环节出发,通过分析陆面耦合指数ILH、潜热通量—抬升凝结高度耦合指数ILCL以及抬升凝结高度ZLCL间接研究中国区域土壤湿度与降水间耦合特征,并对1958~2013年及RCP4.5辐射强迫情景下50年(2006~2055年)的4个代表性区域夏季耦合强度的年代际变化特征进行分析。研究发现:1958~2013年期间,内蒙古阴山山脉附近、新疆和青海的部分地区为夏季中国土壤湿度与降水耦合的最强区域;陆面耦合指数ILH变化幅度从高到低依次出现在华北、华南、内蒙古中部和西北地区,并在20世纪70年代中到80年代中发生转折。2006~2055年的平均而言,预估内蒙古阴山山脉附近仍为耦合最强区;与历史时期(1958~2005年)比较,新疆中部和内蒙古阴山山脉附近的耦合指数ILH增大,而广西和广东地区的则减小;对于耦合指数ILH的年代际变化(2006~2055年),2026~2035年间华北最大而华南最小,西北地区变化不大,而内蒙古中部地区的耦合强度逐渐增大。  相似文献   

Simulation of Precipitation in Monsoon Regions of China by CMIP3 Models   总被引：1，自引：0，他引：1       下载免费PDF全文

TU Kai  YAN Zhong-Wei  ZHANG Xue-Bin  DONG Wen-Jie 《大气和海洋科学快报》2009,2(4):194-200

The output of 25 models used in the Coupled Model Intercomparison Project phase 3 （CMIP3） were evaluated, with a focus on summer precipitation in eastern China for the last 40 years of the 20th century. Most models failed to reproduce rainfall associated with the East Asian summer monsoon （EASM）, and hence the seasonal cycle in eastern China, but provided reasonable results in Southwest （SW） and Northeast China （NE）. The simulations produced reasonable results for the Yangtze-Huai （YH） Basin area, although the Meiyu phenomenon was underestimated in general. One typical regional phenomenon, a seasonal northward shift in the rain belt from early to late summer, was completely missed by most models. The long-term climate trends in rainfall over eastern China were largely underestimated, and the observed geographical pattern of rainfall changes was not reproduced by most models. Precipitation extremes were evaluated via parameters of fitted GEV （Generalized Ex- treme Values） distributions. The annual extremes were grossly underestimated in the monsoon-dominated YH and SW regions, but reasonable values were calculated for the North China （NC） and NE regions. These results suggest a general failure to capture the dynamics of the EASM in current coupled climate models. Nonetheless, models with higher resolution tend to reproduce larger decadal trends and annual extremes of precipitation in the regions studied.  相似文献   

一个灵活的海洋——大气耦合环流模式   总被引：33，自引：13，他引：20  

Yu Yongqiang  Yu Rucong  Zhang Xuehong  Liu Hailong 《大气科学进展》2002,19(1):169-190

Based on the National Center for Atmospheric Research (NCAR) Climate System Model version 1(CSM-1), a Flexible coupled General Circulation Model version 0 (FGCM-0) is developed in this study through replacing CSM-1＇s oceanic component model with IAP L30T63 global oceanic general circulation model and some necessary modifications of the other component models. After the coupled model FGCM--0 is spun up for dozens of years, it has been run for 60 years without flux correction. The model does not only show the reasonable long-term mean climatology, but also reproduce a lot of features of the interannual variability of climate, e.g. the ENSO-like events in the tropical Pacific Ocean and the dipole mode pattern in the tropical Indian Ocean. Comparing FGCM-0 with the NCAR CSM-1, some common features are found, e.g. the overestimation of sea ice in the North Pacific and the simulated double ITCZ etc.The further analyses suggest that they may be attributed to errors in the atmospheric model.  相似文献   

Forecasting extreme events in the tropical Indian Ocean sector climate     

Roxana C. Wajsowicz   《Dynamics of Atmospheres and Oceans》2005,39(1-2):137

Prospects for forecasting climate variability over the tropical Indian Ocean sector, specifically extreme positive events of the Indian Dipole Mode (IDM), with lead times of a season or more are investigated using the NASA Seasonal-to-Interannual Prediction Project (NSIPP) coupled-model system. The coupled system presents biases in its climatology over the Indian Ocean sector, which include (i) warmest sea-surface temperatures (SSTs) occurring in the central equatorial basin rather than on the eastside with the eastern (western) tropical SSTs up to 1 °C too cool (warm), (ii) a too northwest lying InterTropical Convergence Zonal over the ocean in boreal fall, (iii) a thermocline shallower (deeper) than observed west of Sumatra-Java (north of Madagascar), (iv) a delay of about a month in the onset (cessation) of the southwest (southeast) monsoon in the west (east) in boreal spring (fall). These biases affect the effectiveness of the SST-clouds-shortwave radiation negative feedback, the sensitivity of SST to wind-stress perturbations, and the character of equatorial coupled ocean-atmosphere modes. Despite these biases, ensemble hindcasts of the SST anomalies averaged over the eastern and western poles of the IDM for the decade 1993–2002, which included extreme positive events in 1994 and 1997/1998, are encouragingly good at 3-months lead. The onset of the 1997/1998-event is delayed by about a month, though the peak and decay are correctly timed. At 6-months lead-time, the forecast at the eastern pole deteriorates with either positive or negative false alarms generated each boreal fall. The forecast at the western pole remains good.  相似文献   

冷暖事件对大气能量循环和纬向平均环流影响的模拟研究   总被引：1，自引：0，他引：1  

张韬  吴国雄  郭裕福 《气象学报》2002,60(5):513-526

利用中国科学院大气物理研究所大气科学与地球流体力学数值模拟国家重点实验室新发展的GOALS 5全球海 陆 气耦合模式研究了暖事件 (ElNi no)和冷事件 (LaNina)对大气能量循环和纬向平均环流的影响 ,并用观测资料进行了对比分析。结果表明 :对于纬向平均资料来说 ,冷、暖事件在热带和副热带地区的大气环流相关量的反相变化特征非常清晰 ,中高纬度地区并不明显。此外 ,还发现 ,暖事件时定常涡动的经向热通量的变化是北半球对流层热带外地区温度异常的主要原因 ,而瞬变波的影响则起抵消作用。冷事件时定常波和瞬变波相互抵消的局地特征也依然存在 ,但瞬变波的影响有所增强。  相似文献   

On the oceanic impact of a data-assimilation method in a coupled ocean-land-atmosphere model     

Clemente A. S. Tanajura  Konstantin P. Belyaev 《Ocean Dynamics》2002,52(3):123-132

 Based on the Kalman filter theory, a new data-assimilation method has been used to improve the 3-D oceanic temperature field of the Center for Ocean-Land-Atmosphere Studies (COLA) coupled general circulation model. This method is applied to assimilate surface and subsurface temperature of in situ measurements from the Pilot Research Moored Array in the Tropical Atlantic project (PIRATA). The assimilation of the PIRATA data produces an improved representation of the thermal state of the ocean and allows a better estimation of other oceanographic quantities, like meridional heat fluxes and zonal currents. The present paper focuses on the tropical Atlantic and, in particular, it contains new reconstructed temperature profiles. One-month forecast experiments during 1999 were performed and the impact of the assimilation is discussed. Received: 24 April 2001 / Accepted: 8 March 2002  相似文献   

A　Coupled　General　Circulation　Model　for　the　Tropical　Pacific　Ocean　and　Global　Atmosphere   总被引：3，自引：0，他引：3  

Zhang Ronghu  Zeng Qingcun  Zhou Guangqing  Liang Xinzhong 《大气科学进展》1995,12(2):127-142

On the basis of Zeng’s theoretical design, a coupled general circulation model (CGCM) is developed with its characteristics different from other CGCMs such as the unified vertical coordinates and subtraction of the standard stratification for both atmosphere and ocean, available energy consideration, and so on. The oceanic component is a free surface tropical Pacific Ocean GCM between 30oN and 30oS with horizontal grid spacing of 1o in latitude and 2o in longitude, and with 14 vertical layers. The atmospheric component it a global GCM with low-resolution of 4o in latitude and 5o in longitude, and two layers or equal man in the vertical between the surface and 200 hPa. The atmospheric GCM includes comprehensive physical processes. The coupled model is subjected to seasonally-varying cycle. Several coupling experiments, ranging from straight forward coupling without flux correction to one with flux correction, and to so-called predictor-corrector monthly coupling (PCMC), are conducted to show the existence and final controlling of the climate drift in the coupled system. After removing the climate drift with the PCMC scheme, the coupled model is integrated for more than twenty years. The results show reasonable simulations of the annual mean and its seasonal cycle of the atmospheric and oceanic circulation. The model also produces the coherent interannual variations of the climate system, manifesting the observed El Ni?o / Southern Oscillation (ENSO).  相似文献   

The Interannual Variability of Climate in a Coupled Ocean-Atmosphere Model   总被引：2，自引：0，他引：2  

Yu Yongqiang  Guo Yufu 《大气科学进展》1995,12(3):273-288

In this paper, the interannual variability simulated by the coupled ocean-atmosphere general circulation model of the Institute of Atmospheric Physics (IAP CGCM) in 40 year integrations is analyzed, and compared with that by the corresponding IAP AGCM which uses the climatic sea surface temperature as the boundary condition in 25 year integrations.The mean climatic states of January and July simulated by IAP CGCM are in good agreement with that by IAP AGCM, i.e., no serious ‘climate drift’ occurs in the CGCM simulation. A comparison of the results from AGCM and CGCM indicates that the standard deviation of the monthly averaged sea level pressure simulated by IAP CGCM is much greater than that by IAP AGCM in tropical region. In addition, both Southern Oscillation (SO) and North Atlantic Oscillation (NAO) can be found in the CGCM simulation for January, but these two oscillations do not exist in the AGCM simulation.The interannual variability of climate may be classified into two types: one is the variation of the annual mean, another is the variation of the annual amplitude. The ocean-atmosphere interaction mainly increases the first type of variability. By means of the rotated EOF, the most important patterns corresponding to the two types of interannual variability are found to have different spatial and temporal characteristics.  相似文献